gsm docs: Add info about sync_to_cluster and jobs using the secrets stanza

[psalajova]

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[danilo-gemoli]

/lgtm

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/retest-required

Remaining retests: 0 against base HEAD e285724 and 2 for PR HEAD ad7a3fd in total

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/retest-required

Remaining retests: 0 against base HEAD 185e5cc and 1 for PR HEAD ad7a3fd in total

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